Predicting an Ultraviolet-tetraherz Double Resonance Spectrum of Formaldehyde

Predicting an Ultraviolet-tetraherz Double Resonance Spectrum of Formaldehyde

Auteur : Emily Elizabeth Fenn

Date de publication : 2006

Éditeur : Massachusetts Institute of Technology, Department of Chemistry

Nombre de pages : 86

Résumé du livre

In preparation for performing a triple resonance experiment to study the Rydberg states of calcium monofluoride (CaF), a double resonance spectrum of formaldehyde will be recorded. A dye laser will populate a level in formaldehyde's first electronically excited state, and pure rotational transitions will be induced by applying a terahertz electric field. A terahertz spectrometer has been built for this purpose, and the principles of terahertz spectroscopy are described. The 4'0 vibronically allowed transition of the A1 A2

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